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Copper-Catalyzed Synthesis of N-Sulfonyl-1,2,3-triazoles: Controlling Selectivity

✍ Scribed by Eun Jeong Yoo; Mårten Ahlquist; Seok Hwan Kim; Imhyuck Bae; Valery V. Fokin; K. Barry Sharpless; Sukbok Chang

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 113 KB
Volume: 46
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.200604241

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## Abstract A one‐pot synthesis of __N__‐sulfonyl‐2‐alkylidene‐1,2,3,4‐tetrahydropyrimidines __via__ a highly selective and copper‐catalyzed multicomponent reaction of sulfonyl azides, terminal alkynes and α,β‐unsaturated imines has been developed. The α,β‐unsaturated imine substrates could be gene