Copper-Catalyzed Oxidative Amination and Allylic Amination of Alkenes
โ Scribed by Liwosz, Timothy W.; Chemler, Sherry R.
- Book ID
- 120636071
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 418 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0947-6539
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๐ SIMILAR VOLUMES
Allylic hydrocarbons are selectively converted to the corresponding allyl amines in good to excellent yield by reaction with aryl hydroxylamines catalyzed by a 1:1 mixture of CuCl and CuCl 2 (10 mol %). Under these conditions unsymmetrical olefins react highly regioselectively with N-functionalizati
The transition metal catalyzed allylic amination of olefins are studied. A screening of catalysts known for the intermediacy of PhNO in the amination of alkene with phenylhydroxylamine reveals that the hydrated copper salt in conjugation with copper powder as reductant has the best catalytic propert