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Copper-Catalyzed Oxidative Amination and Allylic Amination of Alkenes

โœ Scribed by Liwosz, Timothy W.; Chemler, Sherry R.


Book ID
120636071
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
418 KB
Volume
19
Category
Article
ISSN
0947-6539

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Cu(I)/Cu(II)-catalyzed allylic amination
โœ Radhey S. Srivastava; Roy Bertrand III; August A. Gallo; Kenneth M. Nicholas ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 477 KB

Allylic hydrocarbons are selectively converted to the corresponding allyl amines in good to excellent yield by reaction with aryl hydroxylamines catalyzed by a 1:1 mixture of CuCl and CuCl 2 (10 mol %). Under these conditions unsymmetrical olefins react highly regioselectively with N-functionalizati

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The transition metal catalyzed allylic amination of olefins are studied. A screening of catalysts known for the intermediacy of PhNO in the amination of alkene with phenylhydroxylamine reveals that the hydrated copper salt in conjugation with copper powder as reductant has the best catalytic propert