𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Copper-Catalyzed Hydrocarboxylation of Alkynes Using Carbon Dioxide and Hydrosilanes

✍ Scribed by Prof. Dr. Tetsuaki Fujihara; Dr. Tinghua Xu; Kazuhiko Semba; Prof. Dr. Jun Terao; Prof. Dr. Yasushi Tsuji

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
330 KB
Volume
50
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: Copper-Catalyzed Hy
ChemInform Abstract: Copper-Catalyzed Hydrocarboxylation of Alkynes Using Carbon Dioxide and Hydrosilanes.
✍ Tetsuaki Fujihara; Tinghua Xu; Kazuhiko Semba; Jun Terao; Yasushi Tsuji 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 60 KB 👁 1 views

## Abstract Copper complexes (I) bearing an N‐heterocyclic carbene ligand are efficient catalysts for the hydrocarboxylation of unsymmetrical or symmetrical alkynes using SiH(OEt)~3~ as reducing agent to give α,β‐unsaturated carboxylic acids as (E)‐isomers.

Highly Regio- and Stereoselective Three-
Highly Regio- and Stereoselective Three-Component Nickel-Catalyzed syn-Hydrocarboxylation of Alkynes with Diethyl Zinc and Carbon Dioxide
✍ Suhua Li; Weiming Yuan; Prof. Dr. Shengming Ma 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 424 KB 👁 1 views

## In memory of Xinwei Ma Activation of carbon dioxide and converting it into useful chemical feedstock have attracted much attention owing to the fact that CO 2 is abundant, inexpensive, nontoxic, and environmentally benign. [1] However, the challenges still to be overcome are its lack of thermod