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Copper-Catalyzed Direct C–H Trifluoromethylation of Quinones

✍ Scribed by Wang, Xi; Ye, Yuxuan; Ji, Guojing; Xu, Yan; Zhang, Songnan; Feng, Jiajie; Zhang, Yan; Wang, Jianbo

Book ID
120503081
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
324 KB
Volume
15
Category
Article
ISSN
1523-7060

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Direct C2-trifluoromethylation of indole
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✍ Ryo Shimizu; Hiromichi Egami; Tatsuya Nagi; Jungha Chae; Yoshitaka Hamashima; Mi 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 306 KB

Direct C2-selective trifluoromethylation of indole derivatives was achieved with Togni's hypervalent iodine reagent and CuOAc as a catalyst in MeOH under mild conditions, affording the desired C2-trifluoromethylated indoles in good yield (up to 90%).