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Copper-Catalyzed Decarboxylative Sulfonylation of α,β-Unsaturated Carboxylic Acids

✍ Scribed by Rokade, Balaji V.; Prabhu, Kandikere Ramaiah


Book ID
125931348
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
605 KB
Volume
79
Category
Article
ISSN
0022-3263

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The stereochemical course of anionic dec
✍ E.J. Corey; Thomas H. Lowry 📂 Article 📅 1965 🏛 Elsevier Science 🌐 French ⚖ 265 KB

Ol-Sulfony' carbanions of structure R-SO,-T (Rl)(R2) ACIDS Mass. 02138 can be generated from optically active precursors R-S02-C (Rl)(R2)(Y) in hydroxylic media and protonated to give optically active products, R-S02-CH(Rl)(R2), with high stereospecificity. This remarkable