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Copper-Catalyzed Cyanation of Heteroaryl Bromides: A Novel and Versatile Catalyst System Inspired by Nature.

✍ Scribed by Thomas Schareina; Alexander Zapf; Wolfgang Maegerlein; Nikolaus Mueller; Matthias Beller

Publisher
John Wiley and Sons
Year
2007
Weight
23 KB
Volume
38
Category
Article
ISSN
0931-7597

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A State-of-the-Art Cyanation of Aryl Bro
A State-of-the-Art Cyanation of Aryl Bromides: A Novel and Versatile Copper Catalyst System Inspired by Nature
✍ Thomas Schareina; Alexander Zapf; Wolfgang MΓ€gerlein; Nikolaus MΓΌller; Matthias πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 136 KB πŸ‘ 2 views

## Abstract A general protocol for the cyanation of aryl halides with the nontoxic cyanide source K~4~[Fe(CN)~6~] using copper catalysis and a ligand system based on 1‐alkylimidazoles is presented. The advantages of this system are the high selectivity, a unique substrate range, easy handling, and