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Copper-catalyzed conjugate addition of organomagnesium reagents to α,β-ethylenic esters: A simple high yield procedure.

✍ Scribed by Gérard Cahiez; Mouad Alami

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
277 KB
Volume
31
Category
Article
ISSN
0040-4039

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Organomanganese (II) reagents XXII. Copp
Organomanganese (II) reagents XXII. Copper-catalyzed conjugate addition of organomanganese reagents to α, β-ethylenic esters.
✍ Gérard Cahiez; Mouad Alami 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 136 KB

## Copper-catalyzed conjugate addition of organomanganese reagents to a, B ethylenic esters easily takes place in THF at O'C, in the presence of 3% CuCl and MejSiCI. Good to moderate yields are obtained from organomanganese reagents preparedfrom organolithium or organomagnesium compounok Recently,

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