𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Copper- and vanadium-catalyzed asymmetric oxidations

✍ Scribed by Carsten Bolm; Gunther Schlingloff; Frank Bienewald

Book ID
104423257
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
383 KB
Volume
117
Category
Article
ISSN
1381-1169

No coin nor oath required. For personal study only.

✦ Synopsis

Two asymmetric metal-catalyzed oxidations are discussed. Chiral copper complexes catalyze enantiospecific Baeyer-Villiger oxidations giving optically active lactones in up to 95% ee. Vanadium complexes have been used in enantioselective sulfide oxidations with hydrogen peroxide.

πŸ“œ SIMILAR VOLUMES

Metal-catalyzed asymmetric oxidations
Metal-catalyzed asymmetric oxidations
✍ Carsten Bolm πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 169 KB πŸ‘ 2 views

Recent advances in enantioselective metal-catalyzed oxidations are presented. Two transformations are discussed in detail: (a) asymmetric Baeyer-Villiger reactions of racemic and prochiral cyclic ketones giving optically active lactones, and (b) sulfide oxidations affording enantiomerically enriched

ChemInform Abstract: Homogeneous Copper-
ChemInform Abstract: Homogeneous Copper-Catalyzed Oxidations
✍ Jarl Ivar van der Vlugt; Franc Meyer πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons βš– 15 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v