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ChemInform Abstract: Metal-Catalyzed Asymmetric Oxidations

✍ Scribed by Carsten Bolm

Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
30
Category
Article
ISSN
0931-7597

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Recent advances in enantioselective metal-catalyzed oxidations are presented. Two transformations are discussed in detail: (a) asymmetric Baeyer-Villiger reactions of racemic and prochiral cyclic ketones giving optically active lactones, and (b) sulfide oxidations affording enantiomerically enriched

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## Abstract For Abstract see ChemInform Abstract in Full Text.

Transition metal catalyzed oxidations. 1
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✍ Karsten Krohn; Jochen KΓΌpke πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 27 KB πŸ‘ 1 views

In connection with the zirconium alkoxide-catalyzed oxidation of primary aromatic [2] and aliphatic [3] amines to nitro compounds, we also investigated the reaction of secondary N-aryl-N-alkyl amines with the system Zr(O-t-Bu) 4 /tert-butyl hydroperoxide (TBHP). Surprisingly, and in contrast to most