Copolymerization. XVII. The Over-all Rate of Copolymerization of Styrene—Diethyl Fumarate 1
✍ Scribed by Walling, Cheves; McElhill, Elizabeth A.
- Book ID
- 126241185
- Publisher
- American Chemical Society
- Year
- 1951
- Tongue
- English
- Weight
- 369 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0002-7863
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Monomer reactivity ratios have been determined from the copolyrnerization of methyl methacrylate with (a) t4C-diethyl maleate and (b) t4C-diethyl fumarate initiated with 1.1' azo-bisisobutyronitrile at 60 °. Values of 354+ 57 and 0 for the methyl methacrylate--diethyl maleate system are very differe
## Abstract The electroinitiated preparation of equimolar copolymers of styrene and diethyl fumarate is described. The reaction medium consisted of these monomers dissolved in a methanol–zinc bromide solution. Rates of polymerization increased with increasing applied current and the copolymer yield