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Copolymerization of ethylene with propylene by MgCl2-containing highly active Ti catalysts

✍ Scribed by Norio Kashiwa; Akira Mizuno; Shuji Minami

Book ID
104690471
Publisher
Springer
Year
1984
Tongue
English
Weight
253 KB
Volume
12
Category
Article
ISSN
0170-0839

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The kinetics of ethylene polymerization with TiCl,/MgCl,/SiO, has been investigated in the range of temperatures between 40 and 90Β°C and in the range of ethylene pressures between 4 and 12.4 kg/cm2. The role of MgCI, was discussed from the dependence of the Mg/Ti ratio on the catalytic activity. The

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## Abstract Copolymerization of ethylene and 1‐butene were performed using the catalyst system TiCl~3~ Β· 1/3 AlCl~3~/MgCl~2~/THF with or without partial activation by AlEt~2~Cl. The catalyst and the copolymers were characterized by IR spectroscopy. The experimental results reveal that partial activ