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Copolymerization of Ethene/1-Dodecene and Ethene/1-Octadecene with the Stereorigid Zirconium Catalyst Systems iPr[FluCp]ZrCl2/MAO and Me2Si[Ind]2ZrCl2/MAO: Influence of the Comonomer Chain Length

✍ Scribed by Koivumaeki, Jari; Fink, Gerhard; Seppaelae, Jukka V.


Book ID
127151364
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
601 KB
Volume
27
Category
Article
ISSN
0024-9297

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It is demonstrated that the catalyst system bis(pentamethylcyclopentadienyl)-zirconium dichloride (Me 5 Cp) 2 ZrCl 2 -methylaluminoxane (MAO) is able to produce random copolymers of ethene and 1-hexene. The 1-hexene incorporation in the copolymers is extremely small. Even in the case of a molar rati