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Coordination properties of tris(dimethylamino)phosphine sulfide

✍ Scribed by Slinkard, William E.; Meek, Devon W.


Book ID
121464316
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
759 KB
Volume
8
Category
Article
ISSN
0020-1669

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The standard molar enthalpies of formation at the temperature 298.15 K of (CH3)2NPCl2(l), {(CH3)2N}2PCl(l), and {(CH3)2N}3P(l) have been determined by reaction calorimetry as -(286.3 2 2.4) kJβ€’mol -1 , -(220.1 2 2.3) kJβ€’mol -1 , and -(112.8 2 2.3) kJβ€’mol -1 , respectively. Enthalpies of vaporization