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Conformation of tris(dimethylamino)phosphine: an MNDO study

✍ Scribed by Worley, S. D.; Hargis, J. H.; Chang, L.; Jennings, W. B.

Book ID
127312328
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
368 KB
Volume
20
Category
Article
ISSN
0020-1669

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The enthalpies of formation of (dimethyl
The enthalpies of formation of (dimethylamino)dichlorophosphine, bis(dimethylamino)chlorophosphine, and tris(dimethylamino)phosphine
✍ H.M.A. Al-Maydama; Arthur Finch; P.J. Gardner; A.J. Head πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 330 KB

The standard molar enthalpies of formation at the temperature 298.15 K of (CH3)2NPCl2(l), {(CH3)2N}2PCl(l), and {(CH3)2N}3P(l) have been determined by reaction calorimetry as -(286.3 2 2.4) kJβ€’mol -1 , -(220.1 2 2.3) kJβ€’mol -1 , and -(112.8 2 2.3) kJβ€’mol -1 , respectively. Enthalpies of vaporization