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Coordination Polymer Route to Wurtzite ZnS and CdS Nanorods

โœ Scribed by Zheng-Ping Qiao; Gang Xie; Jun Tao; Zhao-Yang Nie; Yan-Zhi Lin; Xiao-Ming Chen

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
220 KB
Volume
166
Category
Article
ISSN
0022-4596

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โœฆ Synopsis

Wurtzite MS nanorods were synthesized from coordination polymer [M(tp)(4,4Y-bipy)] at 1403C under solvothermal condition (M โ€ซุโ€ฌ Zn, Cd). The morphology determined by TEM gives the average diameters of width/ length as 50/200 nm and 20/75 nm for ZnS and CdS, respectively. X-ray powder di4raction and XPS spectra proved that the as-prepared products were pure ZnS and CdS, respectively.

2002 Elsevier Science (USA)

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## Abstract A facile ligand exchange approach for surfaceโ€functionalized ZnS nanoparticles (NPs) with 5โ€(2โ€methacryloylethyloxymethyl)โ€8โ€quinolinol (MQ) is described. The MQโ€“ZnS NPs, with a cubic crystal structure, have the same diameter as ZnS NPs without MQ about 3.0โ€‰nm. The MQโ€“ZnS NPs exhibit st