Coordination compounds of platinum(II) and palladium(II) with pyrazole as a ligand. New synthetic procedures and characterisation
β Scribed by Cornelis G. van Kralingen; Johannes K. de Ridder; Jan Reedijk
- Book ID
- 105177976
- Publisher
- Springer
- Year
- 1980
- Tongue
- English
- Weight
- 443 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0340-4285
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π SIMILAR VOLUMES
Equimolar quantities of [MI2(CO)3(NCMe)2 ] (M = Mo or W) and C3H4N2 (pyrazole) react in CH2C12 at room temperature to give the iodo-bridged dimers [M(#-I)(CO)3(C:~H~N2)]2 (I) and (2). Two equivalents of C3H4N 2 react with [MIz(CO)a(NCMe)2] (M = Mo or W) to give the bis(pyrazole) complexes [MIz(CO)3(
Pyridine ligands / Bidentate bridging ligands / Palladium / Platinum / N ligands The synthesis of the new potentially tridentate ligand 3,5-contain ligand 3 bonded to 2 metal centres by bridging through coordination of one trialkyl N donor atom and the bis(dimethylaminomethyl)pyridine ( 3) is descr