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Coordination compounds of imidazoles with rhodium halides

✍ Scribed by Jatindra N. Ganguli; Tankeswar Bora


Publisher
Springer
Year
1984
Tongue
English
Weight
422 KB
Volume
9
Category
Article
ISSN
0340-4285

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An efficient copper-catalyzed coupling o
✍ Ayumu Kiyomori; Jean-FranΓ§ois Marcoux; Stephen L. Buchwald πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 230 KB

Copper-catalyzed N-arylation of imidazoles can be accomplished using (CuOTf)2Β°benzene as a copper source and Cs2CO3 as a base in xylenes at 110-125 Β°C. Addition of 1,10-phenanthroline (phen) and trans, trans-dibenzylideneacetone (dba) was crucial to the success of the process. The products, N-arylim