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Coordination Chemistry of {[Zr]−Cl−[Zr]}+ Complexes

✍ Scribed by Heiko Jacobsen; Thomas Brackemeyer; Heinz Berke; Gerhard Erker; Roland Fröhlich


Book ID
101351123
Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
373 KB
Volume
2000
Category
Article
ISSN
1434-1948

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Selective reduction of aldehydes via BIN
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An easily assembled catalyst from (±)-BINOL (1,1%-bi-naphthol) and Zr(O i Pr) 4 • i PrOH selectively reduces aldehydes at room temperature. Ketones remain intact under these conditions. A catalytic amount of BINOL-Zr complex in the presence of 2-propanol also effectively reduces a variety of chiral