𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Coordination Chemistry and Catalysis. Investigations on the Synthesis of Cyclooctatetraene by the Method of W. Reppe

✍ Scribed by Priv.-Doz. Dr. G. N. Schrauzer; P. Glockner; S. Eichler

Publisher
John Wiley and Sons
Year
1964
Tongue
English
Weight
654 KB
Volume
3
Category
Article
ISSN
0044-8249

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✦ Synopsis

In addition to thermal isomerization, pyrolytic reactions also make it possible to convert alkenes into compounds (0.g. diols and triols) in which the functional groups are bound to certain carbon atoms depending on the boron heterocycles formed as intermediates.

The pyrolytic transformations of organoboranes are not limited to compounds containing B-C and B-H bonds. Well-defined B-N heterocycles can also be prepared from organic compounds containing boron-nitrogen bonds [60]. In the case of compounds containing oxygen in addition to boron, the possibilities of preparing the corresponding B -0 heterocycles appear to be slight. I n this case, boroxines are mostly formed instead of heterocycles containing boron and oxygen as well as carbon.

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