Coordination catalysis: The oxidation of amino acids and peptides by dioxygen in the presence of transition metal ions
β Scribed by A. Dempsey; D.A. Phipps
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 225 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0020-1693
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π SIMILAR VOLUMES
Environmentally friendly oxidizing agents such as hydrogen peroxide or dioxygen can be used today in catalytic versions of the almost one century old Baeyer-Villiger oxidation with transition metal complexes as catalysts. On the right is a sketch of a possible mechanism for this reaction with a plat
Multi-metallic hydrotalcites consisting of magnesium, aluminum, and iron, or copper elements were prepared, which catalyzed the Baeyer-Villiger oxidation using a combination system of molecular oxygen and benzaldehyde. In particular, the Mg-Al\(\mathrm{Fe}-\mathrm{CO}_{3}\) hydrotalcite efficiently