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Coordination and fragmentation of 1,4-dithiacyclohexane by a triosmium cluster

โœ Scribed by Richard D. Adams; Linfeng Chen; John H. Yamamoto


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
714 KB
Volume
229
Category
Article
ISSN
0020-1693

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Homogeneous hydrogenation of 1-hexene to hexane was studied using a triruthenium cluster containing a face-capping ligand, HRu,(CO)g(~X-~3-l,3-dithiacyclohexane) (l), as a catalyst precursor. The catalytic activity of 1 was studied as a function of temperature (98-14O"C), H2 pressure ( IO-60 bar) an

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