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Cooperative Ligand Effects in Phase-Switching Homogeneous Catalysts

✍ Scribed by Molise Mokhadinyana; Simon L. Desset; Prof. D. Bradley G. Williams; Prof. David J. Cole-Hamilton


Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
565 KB
Volume
51
Category
Article
ISSN
0044-8249

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## Abstract **Katalysator auf Wanderschaft**: Rhodiumkomplexe mit PPh~3~‐Liganden, die mit schwach basischen Amidingruppen funktionalisiert sind, wirken als hochaktive Katalysatoren fΓΌr die Hydroformylierung von Alkenen. In Gegenwart von Wasser bewegen sich die gelben Rhodiumkomplexe beim Einleiten

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THF) was added [Cp,TiCI,] (2.00 g, 8.03 mmol) in 150 mL of T H F with stirring. After completion of the addition, the mixture was heated to reflux for 48 h. The reaction mixture slowly turned to a deep blue purple. After cooling and filtering, the solvent was evaporated and the residue dissolved in