𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Conversion of α,β-unsaturated ketones into α-hydroxy ketones using an MnIII catalyst, phenylsilane and dioxygen: acceleration of conjugate hydride reduction by dioxygen

✍ Scribed by Philip Magnus; Andrew H Payne; Michael J Waring; David A Scott; Vince Lynch


Book ID
104211274
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
111 KB
Volume
41
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


Treatment of a variety of a,b-unsaturated ketones with Mn(dpm) 3 (3 mol%)/PhSiH 3 (1.3 equiv.)/ isopropyl alcohol/O 2 , followed by reductive work-up with P(OEt) 3 resulted in the formation of a-hydroxyketones.


📜 SIMILAR VOLUMES