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Conjugate reduction of α,β-unsaturated ketones using an MnIII catalyst, phenylsilane and isopropyl alcohol

✍ Scribed by Philip Magnus; Michael J Waring; David A Scott

Book ID
104211275
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
53 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis

Treatment of a variety of a,b-unsaturated ketones with Mn(dpm) 3 (3 mol%)/PhSiH 3 (1.3 equiv.)/isopropyl alcohol with the exclusion of air resulted in the formation of the saturated ketone.

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Conversion of α,β-unsaturated ketones in
Conversion of α,β-unsaturated ketones into α-hydroxy ketones using an MnIII catalyst, phenylsilane and dioxygen: acceleration of conjugate hydride reduction by dioxygen
✍ Philip Magnus; Andrew H Payne; Michael J Waring; David A Scott; Vince Lynch 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 111 KB

Treatment of a variety of a,b-unsaturated ketones with Mn(dpm) 3 (3 mol%)/PhSiH 3 (1.3 equiv.)/ isopropyl alcohol/O 2 , followed by reductive work-up with P(OEt) 3 resulted in the formation of a-hydroxyketones.