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Conversion of α acetylenic alcohols into αβ unsaturated aldehydes

✍ Scribed by Marc Julia; Christian Lefebvre


Book ID
104229927
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
151 KB
Volume
25
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES


Conversion of α,β-unsaturated aldehydes
✍ Yeong-Ho Chang; David E. Campbell; Harold W. Pinnick 📂 Article 📅 1977 🏛 Elsevier Science 🌐 French ⚖ 197 KB

There are a variety of methods for converting the double bond of Michael acceptors into cyclopropanes (eq. 1).2 In contrast, there is no direct way to prepare the cyclopropane as in equation 2. 3

The Rearrangement of α-Acetylenic Alcoho
✍ Horst Pauling; David Arthur Andrews; Nathan Chadwick Hindley 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 German ⚖ 741 KB

## Abstract New catalytic systems have been found which effect the isomerization of α‐acetylenic alcohols to the corresponding α, β‐unsaturated carbonyl compounds with high efficiency. These are combinations of silylvanadates with silanols or silanediols.