Conversion of Thianthrene-5-oxide to Dibenzothiophene by n-Butyllithium
β Scribed by Gilman, Henry; Swayampati, Dhairyasheel R.
- Book ID
- 125899659
- Publisher
- American Chemical Society
- Year
- 1955
- Tongue
- English
- Weight
- 407 KB
- Volume
- 77
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Lithium hydrazonides, prepared by reactions of hydrazones with n-BuLi/hexane in THF at -78Β°C, are converted by azidotris(diethylamino)phosphonium bromide in THF at 0Β°C efficiently, rapidly, and safely to their corresponding diazo compounds along with tris(diethylamino)phosphorimine, nitrogen, and li
Lithium derivatives of varied aromatic, heterocyclic, aliphatic, and alicyclic primary amines react efficiently with azidotris(diethylamino)phosphonium bromide in THF at low temperatures to give azides, lithium bromide, nitrogen, and tris(diethylamino)phosphorimine.