Conversion of prelaureatin into laurallene, a bromo-allene compound, by enzymatic and chemical bromo-etherification reactions

ChemInform Abstract: Conversion of Prela

ChemInform Abstract: Conversion of Prelaureatin into Laurallene, a Bromo-Allene Compound, by Enzymatic and Chemical Bromo-Etherification Reactions.

✍ J. ISHIHARA; Y. SHIMADA; N. KANOH; Y. TAKASUGI; A. FUKUZAWA; A. MURAI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

Conversion of Prelaureatin into Laurallene, a Bromo-Allene Compound, by Enzymatic and Chemical Bromo-Etherification Reactions. -The (E) isomer of prelaureatin is found to react with 2,4,4,6-tetrabromo-2,5-cyclohexadienone and NaBr/H2O2/lactoperoxidase to afford laurallene (II). Starting from the (Z