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ChemInform Abstract: Conversion of Prelaureatin into Laurallene, a Bromo-Allene Compound, by Enzymatic and Chemical Bromo-Etherification Reactions.

✍ Scribed by J. ISHIHARA; Y. SHIMADA; N. KANOH; Y. TAKASUGI; A. FUKUZAWA; A. MURAI

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199743256

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✦ Synopsis

Conversion of Prelaureatin into Laurallene, a Bromo-Allene Compound, by Enzymatic and Chemical Bromo-Etherification Reactions.

-The (E) isomer of prelaureatin is found to react with 2,4,4,6-tetrabromo-2,5-cyclohexadienone and NaBr/H2O2/lactoperoxidase to afford laurallene (II). Starting from the (Z) isomer (deuterated form) laurallene (II) is not formed or in very small amounts. -(ISHIHARA,

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