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Conversion of alcohols to bromides using a fluorous phosphine

โœ Scribed by Laurence Desmaris; Nathalie Percina; Louis Cottier; Denis Sinou


Book ID
108284706
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
181 KB
Volume
44
Category
Article
ISSN
0040-4039

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The conversion of primary and secondary alcohols to chlorides and bromides using 1,2-bis(diphenylphosphino)ethane (diphos) is described. Use of this reagent in lieu of the typical triphenylphosphine-carbontetrahalide complex provides a facile means of purifying the desired halide from the phosphine-

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