Conversion of 2-deoxy-d-ribose into 2-amino-5-(2-deoxy-?-d-ribofuranosyl)pyridine, 2?-deoxypseudouridine, and other C-(2?-deoxyribonucleosides)
✍ Scribed by Reese, Colin B.; Wu, Qinpei
- Book ID
- 121495770
- Publisher
- Royal Society of Chemistry
- Year
- 2003
- Tongue
- English
- Weight
- 262 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1477-0520
- DOI
- 10.1039/B306341K
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📜 SIMILAR VOLUMES
## Abstract A new protected 2‐deoxy‐D‐ribose derivative, 5‐__O__‐[(__tert__‐butyl)diphenylsilyl]‐2‐deoxy‐3,4‐__O__‐ isopropylidene‐__aldehydo__‐D‐ribose (5), was synthesized starting from 2‐deoxy‐D‐ribose. This compound was coupled with 2‐lithio‐4‐(4,5‐dihydro‐4,4‐dimethyloxazol‐2‐yl)pyridine givin
An unnatural base pair, 2-amino-6-(N,N-dimethylamino)purine (denoted x) and pyridin-2-one (denoted y), was designed to prove the structural requirements for base pair formation involving shape complementarity. It was expected that y might satisfy the structural requirements for pairing with x, in wh