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Conversion of 1,4-naphthalenediol to 1,4-naphthoquinone by 1,4-benzoquinone

✍ Scribed by Jyotirekha G Handique; Jubaraj B Baruah

Publisher: Elsevier Science
Year: 2002
Tongue: English
Weight: 149 KB
Volume: 184
Category: Article
ISSN: 1381-1169
DOI: 10.1016/s1381-1169(01)00515-5

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✦ Synopsis

1,4-Naphthalenediol gets converted to 1,4-naphthoquinone on reaction with 1,4-benzoquinone. In the reaction, 1,4-benzenediol is formed. The reaction passes through charge delocalisation in the equivalent keto and enol forms. The spectroscopic and electrochemical studies discern the role of equivalent charge transfer complex derived from 1,4-naphthoquinone with 1,4-benzenediol (A). The conversion of 1,4-naphthalenediol to 1,4-naphthoquinone in the presence of oxidants such as hydrogen peroxide and t-butylhydroperoxide are catalysed by 1,4-benzoquinone

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