Conversion of 1,1-dichloro-2-alkylcyclopropanes to allenes and cyclopropanes
β Scribed by Ted J. Logan
- Book ID
- 108383212
- Publisher
- Elsevier Science
- Year
- 1961
- Tongue
- French
- Weight
- 141 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
sium iodide in ether under reflux into highly sterically hindered alkohols. The mechanism proceeds by a pseudo pinacol type rearrangement of the initially formed carbonyl adduct. The mechanism of the rearrangement was proven by the synthesis of authentic reaction intermediates. The rearrangement was
## C1 c 1 (3) were formed together with (1). The NMR parameters of (l), its cis and trans isomers and (2) were obtained in C,D, solution at 100 MHz. Theoretical spectra of (1) at 60 MHz were simulated with the aid of a computer, using as input the NMR parameters obtained at 100 MHz and good agree