Convergent synthesis of the ABC-ring moiety of zoanthenol: intramolecular Mizoroki–Heck reaction

✍ Scribed by Go Hirai; Hiroki Oguri; Sameh M Moharram; Koji Koyama; Masahiro Hirama

• Book ID: 104231171
• Publisher: Elsevier Science
• Year: 2001
• Tongue: French
• Weight: 85 KB
• Volume: 42
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)01110-8

✦ Synopsis

The highly congested ABC-ring moiety of zoanthenol was stereoselectively synthesized via an alkoxylithium-mediated coupling between the A-ring and C-ring moieties followed by a Mizoroki-Heck-type ring closure.