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Convenient synthesis of optically active iron acyls

✍ Scribed by R.W. Hungate; F. Miller; M.S. Goodman

Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
213 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis

The synthesis of iron acyls derived from Cp(C0)2FeNa which incorporate optically active a amino acids is described. Transition metal acyls have received considerable attention recently and in spite of this activity, there appears to be no report where an optically active a-amino acid is incorporated as the acyl portion.' We have initiated studies to examine the synthesis and reactions of protected amino acids covalently attached to transition metals and as optically active precursors for a-hydroxy B-amino acids.* Initially, we have concentrated on the readily available organometallic anion, Cp(CO)*FeNa, 3 in anticipation of producing iron acyls of general structure I.

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