The synthesis of iron acyls derived from Cp(C0)2FeNa which incorporate optically active a amino acids is described. Transition metal acyls have received considerable attention recently and in spite of this activity, there appears to be no report where an optically active a-amino acid is incorporated
A convenient synthesis of optically active phenylglycine
✍ Scribed by Monique Calmes; Jacques Daunis; Nathalie Mai; François Natt
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 124 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The reaction of O‐menthyl phenylphosphonite **__1__** with aromatic aldehydes in the presence of Me~3~SiCl provided the O‐menthyl α‐hydroxyphosphinates **__2__**. Acidic hydrolysis of **__2__** gave the corresponding α‐hydroxyphosphinic acids **__3__**. The (+)‐enantiomer of **__3a__**
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
2,3-Didehydro-1,2-bis(methoxycarbonyl)-6-methoxypiperidine (4), prepared from l-lysine by using electrochemical oxidation, was cyclopropanated with high diastereoselectivity (96.6% de), and the cyclopropanated product was transformed to optically active 2,3-methanopipecolic acid (1). In this transfo