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Convenient synthesis of hex-1-enopyran-3-uloses: selective oxidation of allylic alcohols using pyridinium dichromate

โœ Scribed by Czernecki, S.; Vijayakumaran, K.; Ville, G.

Book ID
120345635
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
547 KB
Volume
51
Category
Article
ISSN
0022-3263

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1,3-Oxazolidines were obtained from the reaction of N-methyl substituted &amino alcohols with pyridinium dichromate in dichloromethane. A single electron transfer mechanism. SET, is proposed to account for the formation of the 1,3-oxazolidines.