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Unexpected 1,3-oxazolidine formation in the attempted oxidation of N-aryl-N-methyl substituted β-amino alcohols using pyridinium dichromate

✍ Scribed by Jari T. Yli-Kauhaluoma; Curtis W. Harwig; Paul Wentworth Jr.; Kim D. Janda

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
279 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

1,3-Oxazolidines were obtained from the reaction of N-methyl substituted &amino alcohols with pyridinium dichromate in dichloromethane.

A single electron transfer mechanism. SET, is proposed to account for the formation of the 1,3-oxazolidines.

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