Convenient synthesis of deuterated aluminium hydrides
✍ Scribed by Roland H. Pawelke; Michael Felderhoff; Claudia Weidenthaler; Ferdi Schüth
- Book ID
- 113897361
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 186 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1359-6462
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S-Y ## 2,2,3,3-[2H4]-l-Iodopentane (8b ) was prepared in four steps @m pmpargVr alcohol and used in the Calkylation of the THP-protected 3-butyne-1-01 (10). Subsequent protective p u p removal of Ilb, semideuteidon of the acetylenic alcohol 126, and further @ansformation by known methods afforded
## Abstract Novel 3,4‐didehydropyroglutamate derivatives, the key intermediates in this synthesis, were obtained from a protected pyroglutamate by the well‐known selenenylation‐oxidative deselenenylation method and were catalytically deuterated using a slow‐addition technique. The obtained deuterat