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Direct synthesis of pure complex aluminium hydrides by cryomilling

✍ Scribed by André Pommerin; Claudia Weidenthaler; Ferdi Schüth; Michael Felderhoff


Book ID
113898271
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
189 KB
Volume
62
Category
Article
ISSN
1359-6462

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Selective bis-hydride reduction of tosyl
✍ Adrie A.M. Houwen-Claassen; A.J.H. Klunder; B. Zwanenburg 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 839 KB

## On treatment with L.&l the I-tosylmethyl substituted exe-IO-oxan-icyclo[S~.l.~b]&c~e~~s 1 and 3 undergo two consecutive, regioselecrive and stereospecific reductions. The first reduction constitutes an S$' displacement of the allylic rosy1 group, the second a 1,2-reduction of the resulting exo-cy