Convenient synthesis of .alpha.-silyl esters
โ Scribed by Fessenden, Ralph J.; Fessenden, Joan S.
- Book ID
- 120182643
- Publisher
- American Chemical Society
- Year
- 1967
- Tongue
- English
- Weight
- 423 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Phosphoenolpyruvate was synthesized in high yield by a simple procedure starting from pyruvic acid and dimethyl trimethylsilyl phosphite through trimethylsilylation, bromination, and the Perkow reaction. The concept of "high energy phosphate bond" was originally proposed by Lipman in 1941. 2) Severa
Reaction between methyl 3-phenyl-3-trimethylsilylpropionate (8) and catalytic quantities of tetrabutylammonium triphenyldifluorosilicate (TBAT) effects desilylation to the corresponding homoenolate, which can be trapped by a variety of electrophiles. Rearrangement of the homoenolate to the more stab