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Convenient syntheses of 1,1,1,3,3,3-hexafluoro-2-organyl-propan-2-ols and the corresponding trimethylsilyl ethers

✍ Scribed by L.A. Babadzhanova; N.V. Kirij; Yu.L. Yagupolskii; W. Tyrra; D. Naumann


Book ID
108282855
Publisher
Elsevier Science
Year
2005
Tongue
French
Weight
306 KB
Volume
61
Category
Article
ISSN
0040-4020

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## Abstract New and effective routes to synthesize 2‐trimethylsilylmethyl‐3‐trimethylsilyl‐1‐propene and its 1,1‐__d__~2~‐ and 1,1,1β€²,1β€²,3,3‐__d__~6~‐isotopomers have been developed, using the displacement reaction of lithium trimethylsilylcyanocuprate with allylic halides and tosylates. These comp