✦ LIBER ✦

Effective Syntheses of 2-trimethylsilylmethyl-3-trimethylsilyl-1-propene and its 1,1-d2- and 1,1,1′,1′,3,3- d6-isotopomers

✍ Scribed by Jun Hu; Robert R. Squires

Publisher: John Wiley and Sons
Year: 2001
Tongue: French
Weight: 92 KB
Volume: 44
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.511

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

New and effective routes to synthesize 2‐trimethylsilylmethyl‐3‐trimethylsilyl‐1‐propene and its 1,1‐d~2~‐ and 1,1,1′,1′,3,3‐d~6~‐isotopomers have been developed, using the displacement reaction of lithium trimethylsilylcyanocuprate with allylic halides and tosylates. These compounds are pivotal precursors for the gas‐phase synthesis and characterization of the trimethylenemethane anion, and for negative ion photoelectron spectroscopic investigations of the singlet–triplet splitting in trimethylenemethane. Copyright © 2001 John Wiley & Sons, Ltd.

📜 SIMILAR VOLUMES

Syntheses of 2-chloro-2-methylpropane-1,

Syntheses of 2-chloro-2-methylpropane-1,1,1,3,3,3-D6, 2-chloro-2-methylpropane-D9, 2,2-dimethyl-D6-propane-1,1,1-D3 and 2,2-dimethyl-propane-D12

📂 Article 📅 1974 🏛 John Wiley and Sons 🌐 French ⚖ 163 KB 👁 1 views

Convenient Syntheses of 1,1,1,3,3,3-Hexa

Convenient Syntheses of 1,1,1,3,3,3-Hexafluoro-2-organyl-propan-2-ols and the Corresponding Trimethylsilyl Ethers.

✍ L. A. Babadzhanova; N. V. Kirij; Yu. L. Yagupolskii; W. Tyrra; D. Naumann 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 26 KB

ChemInform Abstract: Effective Synthesis

ChemInform Abstract: Effective Synthesis of 1,2-Di-, 1,2,3-Tri-, 1,2,3,3-Tetraalkyldiaziridines and 1,5-Diazabicyclo[3.1.0]hexanes.

✍ Nina N. Makhova; Anatolii N. Mikhailyuk; Vladimir V. Kuznetsov; Sergei A. Kutepo 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

Syntheses of 1,2-Di- and 1,2,3-Trialkyld

Syntheses of 1,2-Di- and 1,2,3-Trialkyldiaziridines.

✍ Vladimir V. Kuznetsov; Nina N. Makhova; Dmitrii E. Dmitriev; Victor V. Seregin 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 15 KB

ChemInform Abstract: Synthesis of Substi

ChemInform Abstract: Synthesis of Substituted Selenolo[3,2-d][1,2,3]triazines and [1,3]Selenazolo[4,5-d][1,2,3]triazines.

✍ Enrico Perspicace; David Thomae; Gregory Hamm; Stephanie Hesse; Gilbert Kirsch; 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 41 KB 👁 1 views

Formation of 1,1,2,3,3-pentakis(arylthio

Formation of 1,1,2,3,3-pentakis(arylthio)-1-propenes from tris(arylthio)cyclopropenyl cations and their conversion into 1,1,2,5,6,6-hexakis(arylthio)-(3E)-1,3,5-hexatriene

✍ Noboru Matsumura; Yasuyo Shimizu; Yoshio Yagyu; Hiroo Inoue; Kazuhiko Mizuno; To 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 257 KB 👁 1 views

## The reaction of tetrachlorocyclopropene (1) with arenethiols (2a-e), followed by treatment with perchloric acid, gave tris(arylthio)cyclopropenylium perchlorates (3a-c and e), 1,1,2,3,3-pentakis(arylthio)-1-propenes (4a-d), and 2,3,3tris(arylthio)propenals (5a-d). The structures of tris(phenylth