Convenient preparations of t-butyl esters and ethers from t-butanol
β Scribed by Stephen W. Wright; David L. Hageman; Ann S. Wright; Lester D. McClure
- Book ID
- 104258094
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 221 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
t-Butyl methyl ether can be metallated directly to afford a reactive and synthetically useful hydroxymethyl anion equivalent. t-Butyl methyl ether (TBME), a cheap @. $'l/iiter) commercial chemical, can be metallated by s-butyllithium -potassium t-butoxide reagent' as evidenced by formation of t-buto
The pyrolysis kinetics of the title compounds has been studied in a stirred-flow reactor over the temperature range 440-530Β°C and pressures between 5 and 14 torr. Benzyl t-butyl sulfide and phenyl t-butyl ether formed isobutene as product in over 98% yield, together with the corresponding benzyl thi