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Convenient Preparation of Dialkyl Diselenides: A Large Scale Synthesis of bis -(2-Hydroxyethyl) Diselenide

โœ Scribed by Jakiwczyk, Olga M.; Kristoff, Eva M.; McPhee, Derek J.


Book ID
120818301
Publisher
Taylor and Francis Group
Year
1993
Tongue
English
Weight
211 KB
Volume
23
Category
Article
ISSN
0039-7911

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The action of samarium diiodide on various keto-seienocyanates led to the chemoselective formation of the diselenide bond under very mild conditions. The flexibility of this method also allowed one to get either dialdehyde-diselenides or dicyanohydrin-dialdehydes from the same parent oxo-selenocyana