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Controlling yield and regioselectivity in the enzymatic synthesis of β-D-galactopyranosyl-β-D-xylopyranosides

✍ Scribed by Rosa López; Alfonso Fernández-Mayoralas


Book ID
104215775
Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
196 KB
Volume
33
Category
Article
ISSN
0040-4039

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✦ Synopsis


Yield and regioselectivity of the galactosidation of I~-D-xylopyranosides catalysed by the ~galactosidase from E. coil can be modulated by the nature of the aglyconic moiety of the xylopyranosides.


📜 SIMILAR VOLUMES


A direct enzymatic synthesis of β-d-gala
✍ Juan J. Aragón; Francisco J. Cañada; Alfonso Fernández-Mayoralas; Rosa López; Ma 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 422 KB

By enzymatic fl-o-galactosylation of D-xylose a mixture of 4-, 3-, and 2-O-fl-D-galactopyranosyl-D-xyloses (1, 4, and 7, respectively) was obtained in 50% isolated yield. Disaccharides 1, 4, and 7 are substrates of intestinal lactase isolated from lamb small intestine with K m values of 250.0, 4.5,