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Controlling Regioselectivity in Enzyme-catalyzed Acylation of Polyhydroxyl Compounds

โœ Scribed by JOSEPH O. RICH; JONATHAN S. DORDICK

Book ID
119873165
Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
214 KB
Volume
799
Category
Article
ISSN
0890-6564

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Controlling enzyme-catalyzed regioselect
Controlling enzyme-catalyzed regioselectivity in sugar ester synthesis
โœ Joseph O. Rich; Bruce A. Bedell; Jonathan S. Dordick ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 863 KB

The rational control over enzyme-catalyzed regioselectivity has been studied using sucrose acylation by vinyl esters in organic media as a model. Subtilisins BPN' and Carlsberg preferentially acylate at the 1 '-hydroxyl of sucrose with some acylation observed at the 6-hydroxyl. The preference for th