Controlling Dielectric and Optical Properties of Ordered Mesoporous Organosilicate Films
✍ Scribed by A.R. Balkenende; F.K. de Theije; J.C.K. Kriege
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 224 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0935-9648
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✦ Synopsis
Mesoporous hybrid inorganic–organic silicate films with pendant methyl groups are prepared. With a high organic fraction, these films are hydrophobic, which is important in the fabrication of low‐k dielectrics. The refractive index of layers with smaller organic fraction can be switched reversibly over a large refractive index interval by varying the relative humidity (see Figure).
📜 SIMILAR VOLUMES
## Abstract The precursors of poly(hydrogen silsesquioxane) (PHSSQ) were synthesized from triethoxysilane (TES) through variations in the pH and molar ratio of water to TES (__R__~1~). The molecular structures of the prepared PHSSQ precursors were controlled by the reaction conditions, including th