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Oblique Incidence Organic Molecular Beam Deposition and Nonlinear Optical Properties of Organic Thin Films with a Stable In-Plane Directional Order

✍ Scribed by Chengzhi Cai; Martin M. Bösch; Bert Müller; Ye Tao; Armin Kündig; Christian Bosshard; Zhehong Gan; Ivan Biaggio; Ilias Liakatas; Matthias Jäger; Hansjörg Schwer; Peter Günter

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 382 KB
Volume: 11
Category: Article
ISSN: 0935-9648
DOI: 10.1002/(sici)1521-4095(199906)11:9<745::aid-adma745>3.0.co;2-5

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Model for In-Plane Directional Ordering

Model for In-Plane Directional Ordering of Organic Thin Films by Oblique Incidence Organic Molecular Beam Deposition

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Supramolecular Materials: Molecular Pack

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Highly stable films of tetranitrotetrapropoxycalix[4]arene (9) with second-order nonlinear optical (NLO) properties and a noncentrosymmetric structure were obtained by a novel crystallization process at 130 ± 140 8C in a dc electric field. The packing of 9 in these films was elucidated by a combinat