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Controlled Radical Polymerization of Methyl Methacrylate in the Presence of Palladium Acetate, Triphenylphosphine, and Carbon Tetrachloride

✍ Scribed by Lecomte, Ph.; Drapier, I.; Dubois, Ph.; Teyssié, Ph.; Jérôme, R.

Book ID
120883461
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
64 KB
Volume
30
Category
Article
ISSN
0024-9297

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✍ Zhong-Xi Huang; Yong-Ming Zhang; Hong Li; Yan-Gang Liu 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 169 KB

## Abstract Using cobalt acetate as a catalyst, the controlled/“living” polymerization of MMA was carried out. PMMA with a predicted molecular weight and a low polydispersity $(\overline M \_{\rm w} /\overline M \_{\rm n} = 1.26)$ was obtained. Using the obtained PMMA as a macroinitiator, a chain e