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Controlled polymerization of alkyl glycidyl ether by a new catalyst system, aryl silyl ether/cesium fluoride

โœ Scribed by Nambu, Yoko; Endo, Takeshi


Book ID
126871523
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
196 KB
Volume
24
Category
Article
ISSN
0024-9297

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A novel reaction for the functionalizati
โœ Yoko Nambu; Takeshi Endo ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 238 KB

By use of cesium fluoride as a catalyst, aryl or alkyl glycidyl ethers were ring-opened by aryl trimethylsilyl ether to produce O-protected aryloxyhydrins with a quantitative regioselectivity for the first time. Alkyl silyl ether was ineffective for this ring-opening. Hy the regioselective ring-ope